Neutral density means just that. They are neutral in colour and all they do is cut down the amount of light reaching the sensor. So rather than shoot at f16, you may be able to knock it back to f8 and thus avoid any diffraction effects. If you were doing a sunset shot a ND filter would allow you to slow the shutter down to get a blurred wave action.
A graduated ND filter only has the shading halfway across the glass so when you are doing a sunset shot you can shade out the sun and bring up anything in the foreground. One time I tipped it on its side and shaded out a nearby brightly lit bridge.
By using a ND filter and a grad at the same time you can slow the shutter to 30 seconds and turn out shots like John Waters does.
I haven't used one to shoot at green stuff but it sounds feasible.
Bill